Non-Resonant Breakdown of the Franck-Condon Approximation as Seen in Vibrational Branching Ratios
نویسندگان
چکیده
منابع مشابه
Global Franck-Condon breakdown resulting from Cooper minima.
Kwanghsi Wang and V. McKoy Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125 (Received 1 December 1995) Using N2 2s21 u photoionization as an example, we present the first measurements and calculations of photoion vibrational distributions for an extended energy range (5 # Ek # 230 eV). The results show a striking breakdown of the F...
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The calculation of Franck-Condon factors between different one-dimensional Morse potential eigenstates using a formula derived from the Wigner function is discussed. Our numerical calculations using a very simple program written in Mathematica is compared with other calculations. We show that our results have a similar accuracy as the calculations performed with more sophisticated methods. We d...
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Departamento de Qúımica, Módulo 13, Universidad Autónoma de Madrid, 28049 Madrid, Spain Department of Physics and Astronomy, University of Turku 20014 Turku, Finland Institute for Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan Dipartimento di Scienze Chimiche, Università di Trieste, 34127 Trieste, and CNR-IOM, Trieste, Italy ‡ Instituto Madrileño de...
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Strong coupling of electronic and vibrational degrees of freedom entails a low-bias suppression of the current through single-molecule devices, termed the Franck-Condon blockade. In the limit of slow vibrational relaxation, transport in the Franck-Condon-blockade regime proceeds via avalanches of large numbers of electrons, which are interrupted by long waiting times without electron transfer. ...
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ژورنال
عنوان ژورنال: Journal of Physics: Conference Series
سال: 2012
ISSN: 1742-6588,1742-6596
DOI: 10.1088/1742-6596/388/2/022061